Raman spectroscopic studies of carbonates part I: High-pressure and high-temperature behaviour of calcite,magnesite, dolomite and aragonite     

Philippe Gillet  Claudine Biellmann  Bruno Reynard  Paul McMillan 《Physics and Chemistry of Minerals》1993,20(1):1-18

The room-temperature Raman spectra of aragonite, magnesite and dolomite have been recorded up to 30 GPa and 25 GPa, respectively and no phase changes were observed during compression, unlike calcite. The effect of temperature on the room-pressure Raman spectra of calcite, aragonite, magnesite and dolomite is reported up to 800–1100 K. The measured relative pressure and temperature-shifts of the Raman lines are greater for the lattice modes than for the internal modes of the CO₃ groups. These shifts are used to calculate the mode anharmonic parameters of the observed Raman modes; they are negative and their absolute values are smaller (close to 0) for the internal CO₃ modes than for the lattice modes (4–17 10^?5 K^?1). The temperature shifts of the lattice modes in calcite are considerably larger than those for dolomite and magnesite, and a marked non-linear increase in linewidth is observed above 400° C for calcite. This is consistent with an increasing relaxational component to the libration of the CO₃ groups about their threefold axes, premonitory to the rotational order-disorder transition at higher temperature. This behaviour is not observed for the other calcite structured minerals in this study. We examine systematic variations in the lattice mode frequencies and linewidths with composition, to begin to understand these differences in their anharmonic behaviour. Finally, we have used a simple Debye-Waller model to calculate atomic displacements in calcite, magnesite and dolomite with increasing temperature from the vibrational frequency data, to provide a direct comparison with atomic positional data from high-temperature structure refinements.  相似文献   

Influence of Mantle Compressibility and Ocean Warping On Dynamical Models of the Geoid     

Catherine Thoraval  Philippe Machetel  Anny Cazenave 《Geophysical Journal International》1994,117(2):566-573

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A 3-D model for the Antarctic ice sheet: a sensitivity study on the glacial-interglacial contrast   总被引：6，自引：1，他引：6  

Philippe Huybrechts 《Climate Dynamics》1990,5(2):79-92

On the longer climatic time scales, changes in the elevation and extent of the Antarctic ice sheet have an important role in modulating global atmospheric and oceanographic processes, and contribute significantly to world-wide sea levels. In this paper, a 3-D time-dependent thermomechanical model for the entire ice sheet is presented, that is subsequently used to examine the effects of glacial-interglacial shifts in environmental boundary conditions on its geometry. The model takes into account a coupled ice shelf, grounding-line dynamics, basal sliding and isostatic bed adjustment and considers the fully coupled velocity and temperature fields. Ice flow is calculated on a fine mesh (40 km horizontal grid size and 10 layers in the vertical) for grounded and floating ice and a stress transition zone in between at the grounding line, where all stress components contribute in the effective stress in the flow law. There is free interaction between ice sheet and ice shelf, so that the entire geometry is internally generated. A simulation of the present ice sheet reveals that the model is able to yield realistic results. A series of sensitivity experiments are then performed, in which lower temperatures, reduced accumulation rates and lower global sea level stands are imposed, either singly or in combination. By comparing results of pairs of experiments, the effects of each of these environmental changes can be determined. In agreement with glacial-geological evidence, we found that the most pronounced changes show up in the West Antarctic ice sheet configuration. They appear to be essentially controlled by variations in eustatic sea level, whereas typical glacial-interglacial changes in temperature and ice deposition rates tend to balance one another. These findings support the hypothesis that the Antarctic ice sheet basically follows glacial episodes in the northern hemisphere by means of sea-level teleconnections. Grounding occurs more readily in the Weddell sea than in the Ross sea and long time scales appear to be involved: it may take up to 30–40000 years for these continental shelf areas to become completely grounded after an initial stepwise perturbation in boundary conditions. According to these reconstructions, a steady state Antarctic ice sheet may contribute some 16 m to global sea level lowering at maximum glaciation.  相似文献   

Isotope and trace element geochemistry of sediments from the Barbados Ridge-Demerara Plain region,Atlantic Ocean     

William M. White  Bernard Dupré  Philippe Vidal 《Geochimica et cosmochimica acta》1985,49(9):1875-1886

Twenty-four piston core sediment samples and 13 sediments and 3 basalts from DSDP Leg 78 Site 543 were analyzed for Sr, Nd and Pb isotopic compositions. The results show sediment with highly radiogenic Pb${}^{206}\text{Pb}{}^{204}\text{Pb}$ up to 19.8) and rather radiogenic Sr and unradiogenic Nd has been deposited in the region since the Cretaceous. The source of this sediment is probably the Archean Guiana Highland, which is drained by the Orinoco River. Pb and Sr isotopic compositions and sediment thickness decrease and${}^{143}\text{Nd}{}^{144}\text{Nd}$ increases northward due to a decrease in turbiditic component. This decrease is partly due to the damming action of basement ridges. Rare earth concentrations in the sediments are somewhat low, due to the abundance of detrital and biogenic components in the sediment and rapid sedimentation rates. Both positive and negative Ce anomalies occur in the surface sediments, but only positive Ce anomalies occur in the Site 543 sediments. It is unlikely that sediment subducted to the source region of Lesser Antilles arc magmas could be the cause of negative Ce anomalies in those magmas.Isotopic compositions of Site 543 basalts show some effect of contamination by seawater-basalt reaction products and sediments. Beyond this, however, they are typical of “normal” depleted MORB.  相似文献   

Present limitations of accurate satellite Doppler positioning for tectonics. An example: Djibouti     

Annie Souriau  Alfred Piuzzi  Micheline Etchegorry  Philippe Machetel 《Journal of Geodesy》1984,58(1):53-72

One of the possibilities of the Doppler positioning from satellite is to provide geodetic measurements continuous in time without the need for reference stations. If measurements of sufficient accuracy can be achieved they may be used to study local surface displacements in relation to tectonic activity. A Doppler receiver of the MEDOC network is located near Djibouti in the Ghoubhat-Asal rift region which corresponds to the accreting plate boundary between the Arabian and African plates. In November 1978, a seismic and volcanic crisis occured in this area. Surface geodetic measurements and levellings performed in 1973 and 1978–79, just after the crisis, reveal a 60–80 cm sinking of the graben floor and a lateral extension of about 2 meters. Here we analyse Doppler measurements for the period January 1977 to November 1980. Point positions are computed for 7 to 10 day intervals using a precise ephemeris, and a moving window analysis is applied to the data. An apparent 2 meter uplift preceding the November 1978 seismic crisis is detected at Djibouti, whereas no similar phenomenon is observed at the two closest stations, Pretoria and Uccle-Brussels. However, field observations rule out a tectonic origin for this uplift. In Djibouti, the correlation between the apparent vertical station position and the electron density in the ionospheric F-layer reveals that a bias may be induced by the third order term of the ionospheric refractive index not previously taken into account, or more probably by the ray curvature through the ionosphere. This bias is particularly strong for our data set, from a station located close to the magnetic equator, and related to a period of rapid increase in the solar activity. Although our analysis fails to detect any tectonic displacement related to the rift seismic activity, it shows that similar tectonic studies by the Doppler method will be possible once the residual ionospheric errors are removed, for example by use of higher radio frequencies.  相似文献   

Eruptive history of the Colima volcanic complex (Mexico)     

Claude Robin  Philippe Mossand  Guy Camus  Jean-Marie Cantagrel  Alain Gourgaud  Pierre M. Vincent 《Journal of Volcanology and Geothermal Research》1987,31(1-2)

The evolution of the Colima volcanic complex can be divided into successive periods characterized by different dynamic and magmatic processes: emission of andesitic to dacitic lava flows, acid-ash and pumice-flow deposits, fallback nuées ardentes leading to pyroclastic flows with heterogeneous magma, plinian air-fall deposits, scoriae cones of alkaline and calc-alkaline nature. Four caldera-forming events, resulting either from major ignimbrite outbursts or Mount St. Helens-type eruptions, separate the main stages of development of the complex from the building of an ancient shield volcano (25 × 30 km wide) up to two summit cones, Nevado and Fuego.The oldest caldera, C1 (7–8 km wide), related to the pouring out of dacitic ash flows, marks the transition between two periods of activity in the primitive edifice called Nevado I: the first one, which is at least 0.6 m.y. old, was mainly andesitic and effusive, whereas the second one was characterized by extrusion of domes and related pyroclastic products. A small summit caldera, C2 (3–3.5 km wide), ended the evolution of Nevado I.Two modern volcanoes then began to grow. The building of the Nevado II started about 200,000 y. ago. It settled into the C2 caldera and partially overflowed it. The other volcano, here called Paleofuego, was progressively built on the southern side of the former Nevado I. Some of its flows are 50,000 y. old, but the age of its first outbursts is not known. However, it is younger than Nevado II. These two modern volcanoes had similar evolutions. Each of them was affected by a huge Mount St. Helens-type (or Bezymianny-type) event, 10,000 y. ago for the Paleofuego, and hardly older for the Nevado II. The landslides were responsible for two horseshoe-shaped avalanche calderas, C3 (Nevado) and C4 (Paleofuego), each 4–5 km wide, opening towards the east and the south. In both cases, the activity following these events was highly explosive and produced thick air-fall deposits around the summit craters.The Nevado III, formed by thick andesitic flows, is located close to the southwestern rim of the C3 caldera. It was a small and short-lived cone. Volcan de Fuego, located at the center of the C4 caldera, is nearly 1500 m high. Its activity is characterized by an alternation of long stages of growth by flows and short destructive episodes related to violent outbursts producing pyroclastic flows with heterogeneous magma and plinian air falls.The evolution of the primitive volcano followed a similar pattern leading to formation of C1 and then C2. The analogy between the evolutions of the two modern volcanoes (Nevado II–III; Paleofuego-Fuego) is described. Their vicinity and their contemporaneous growth pose the problem of the existence of a single reservoir, or two independent magmatic chambers, after the evolution of a common structure represented by the primitive volcano.  相似文献   

Une mégaséquence d'émersion: la Lettenkohle (Trias Est de la France). Mise en évidence de marées par l'imbrication bipolaire de plaques de dessiccation     

Philippe Duringer 《International Journal of Earth Sciences》1987,76(2):579-597

Résumé Dès la partie moyenne du Muschelkalk supérieur, les faciès marins francs deviennent de moins en moins profonds. Avec l'avènement de la Lettenkohle, la transgression marine à son maximum dans le Muschelkalk supérieur, semble s'épuiser. Le caractère régressif est attesté par le relais de faciès récifaux, par des dépÔts littoraux et des marais cÔtiers. Cette évolution est marquée par l'édification d'une mégaséquence d'émersion complète. Des indices de marées sous forme d'imbrications bipolaires de plaques de dessiccation ainsi que des chenaux tidaux ont été observés. Certaines structures tidales ont été comparées avec celles de l'estran du Mont-Saint-Michel en Normandie (France).

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From the Middle Upper Muschelkalk the marine facies are becoming less deep. At the beginning of the Lettenkohle the marine transgression which had reached a maximum in the Upper Muschelkalk now seems to decline. Regression is evidenced by progressive replacement of reef facies by coastal deposits and supratidal marshes. The process results in the erection of the coarsening upward cycle of a progressive complete emergence.The trace of tides, i.e. bipolar desiccation clast fabric as well as tidal channels have been observed. Some tidal structures are compared with those of the depositional environment of Mont Saint Michel (Normandie).

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Zusammenfassung Schon im mittleren Oberen Muschelkalk zeigen die vollmarinen Fazies eine allmähliche Verringerung der Meerestiefe. Mit dem Auftreten der Lettenkohle scheint die im Oberen Muschelkalk optimale Transgression langsam abzuklingen. Ein progressiver übergang von einer marinen Riffbildung zu einem Küstenlandmoor veranschaulicht eine Regression. Dieser Vorgang bildet die Megasequenz einer progressiven totalen Emersion.Gezeiteneinflüsse werden an eingeregelten Trockenri\klasten und Rinnen beobachtet. Wattgefüge werden mit denen des heutigen Wattablagerungsmilieu des Mont Saint Michel in der Normandie verglichen.

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. . . , . - . , , Mont Saint Michel .

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Isotopic study of the Manaslu granite (Himalaya,Nepal): inferences on the age and source of Himalayan leucogranites   总被引：17，自引：1，他引：17  

Catherine Deniel  Philippe Vidal  Angel Fernandez  Patrick Le Fort  Jean-Jacques Peucat 《Contributions to Mineralogy and Petrology》1987,96(1):78-92

A detailed isotopic study of the Manaslu leucogranite was carried out. A U-Pb age of 25 Ma and a whole rock Rb-Sr age isochron of 18 Ma were obtained, suggesting that the magmatic activity lasted at least 7 Ma. Initial Sr isotopic ratios are very high (0.740 to 0.760) and initial Nd isotopic ratios are low ( _Nd ⁱⁿ : –13 to –16), and they show the existence of large isotopic variations even at the metre scale. These are not the result of perturbations by fluids but rather they reflect the initial isotopic heterogeneity of the source material which has not been obliterated by magmatic processes (e.g. fusion, mixing by convection). These results also support the crustal origin of this leucogranite. The Tibetan slab paragneisses, whose Sr and Nd isotopic ratios are very similar to those of the granite at an age of 20 Ma, are the most probable parental material. Nd model ages for both the leucogranite and the gneisses are in the range 1.5–2 Ga. A model of formation of the Manaslu granite by coalescence of different batches of magma is in agreement with the present data.  相似文献   

Etude des Déformations et Inclinaisons du Sous-sol: Développements Instrumentaux et Applications dans la Région Sismique d’Arette,France     

Philippe Lesage  Pierre Antoine Blum  Marcel Vadell  Jean Francois Fels 《Pure and Applied Geophysics》1983,121(5-6):889-902

We present a modified version of a tilt and strain meter conceived to have great sensibility and good stability. These instruments were deployed in a cave at the seismic Pyrenean region of Arette (France). We set in evidence several types of phenomena, of which deformations brought about by water recharge filling up fissures on the massif are of importance. Owing to the redundance in the data, the study of the co-seismic deformations allows one to separate instrumental displacements and local readjustments from regional motions.  相似文献   

Evaluation of a high-resolution regional climate simulation over Greenland     

Filip Lefebre  Xavier Fettweis  Hubert Gallée  Jean-Pascal Van Ypersele  Philippe Marbaix  Wouter Greuell  Pierluigi Calanca 《Climate Dynamics》2005,25(1):99-116

A simulation of the 1991 summer has been performed over south Greenland with a coupled atmosphere–snow regional climate model (RCM) forced by the ECMWF re-analysis. The simulation is evaluated with in-situ coastal and ice-sheet atmospheric and glaciological observations. Modelled air temperature, specific humidity, wind speed and radiative fluxes are in good agreement with the available observations, although uncertainties in the radiative transfer scheme need further investigation to improve the model’s performance. In the sub-surface snow-ice model, surface albedo is calculated from the simulated snow grain shape and size, snow depth, meltwater accumulation, cloudiness and ice albedo. The use of snow metamorphism processes allows a realistic modelling of the temporal variations in the surface albedo during both melting periods and accumulation events. Concerning the surface albedo, the main finding is that an accurate albedo simulation during the melting season strongly depends on a proper initialization of the surface conditions which mainly result from winter accumulation processes. Furthermore, in a sensitivity experiment with a constant 0.8 albedo over the whole ice sheet, the average amount of melt decreased by more than 60%, which highlights the importance of a correctly simulated surface albedo. The use of this coupled atmosphere–snow RCM offers new perspectives in the study of the Greenland surface mass balance due to the represented feedback between the surface climate and the surface albedo, which is the most sensitive parameter in energy-balance-based ablation calculations.  相似文献